Mass-independent Isotope Anomalies of Titanium in Carbonaceous Chondrites: Implications for Isotopic Heterogeneity in the Early Solar System

The isotopic compositions of meteorites provide valuable insights into the earliest history of the Solar System and, in some cases, provide constraints on presolar components that contributed to the solar nebula. In the past decade or so, mass-independent isotope anomalies in titanium have become particularly important geochemical tracers to study the distinct isotopic reservoirs in the early Solar System. In particular, mass-independent anomalies in the most neutron-rich isotope of titanium (50Ti) have been used to distinguish between carbonaceous chondritic (CC) and non-carbonaceous chondritic (NC) materials. These two groupings likely represent distinct isotopic reservoirs in the inner (NC) and outer (CC) Solar System. However, while the titanium isotope compositions of CC and NC materials are distinct, each group's full range of compositional variability is poorly characterized. For example, only one CK carbonaceous chondrite group member has been analyzed thus far for its bulk Ti isotope composition. This work aims to characterize better the range of mass-independent Ti isotope compositions within and among the carbonaceous chondrites, which has implications for the degree and potential sources of Ti isotope heterogeneity in the early Solar System. Methods utilized in this study include column chromatography to purify Ti and high-precision multi-collector inductively coupled plasma mass spectrometry for measuring Ti isotope compositions. The Ti isotope compositions of bulk samples of nine carbonaceous chondrites are reported here. In addition, the bulk fractions of the meteorites used in this study were taken from homogenized powders of relatively large (~200 mg each) samples. This was done to assess whether variability in mass-independent Ti isotope compositions previously reported within some meteorites could be a sampling artifact. Results from this work show that the various CM2 chondrites and ungrouped carbonaceous chondrites have ε50Ti values that are similar, suggesting that the Ti in these samples was likely sourced from a common isotopic reservoir. On the other hand, the ε50Ti values reported for CI1 and CH/CBb bulk samples suggest that the parent bodies of these carbonaceous chondrite groups were formed in isotopic reservoir(s) distinct from that of the other CC groups in the early Solar System.